[50][51] Other drugs among adamantane derivatives include adapalene, adapromine, bromantane, carmantadine, chlodantane, dopamantine, memantine, rimantadine, saxagliptin, tromantadine, and vildagliptin. Chem. A method for enantiodivergent production of S and R propargylic alcohols from their racemates by using commercial lipase-based dynamic kinetic resolution achieves quantitative conversion of the racemates into optically pure substances. Adamantane was recently identified as a key structural subunit in several synthetic cannabinoid designer drugs, namely AB-001 and SDB-001. a Shanghai Institute of Organic Chemistry, Zhejiang Medicine Co., and Pharmaron postdoctoral fellowship (J.W. 52, 85698572 (2016). eg. Ertl, P. & Schuhmann, T. A systematic cheminformatics analysis of functional groups occurring in natural products. 20, 78467850 (2018). Most reactions owe their efficiency to neighboring double bonds or oxygen and nitrogen atoms that linger in the products. [2][3] He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. Intermediate Organic Chemistry, Third Edition., by Ann M. Fabirkiewicz and John C. Stowell. ACS Catal. Li, Z. et al. J. For this achievement, he was awarded the Nobel Prize in Chemistry in 2010. No headers Constitutional or structural isomers are compounds with the same molecular formula but different structural formulas.. eg. Since the charge of cation formed in the mass spectrometer is almost always +1, the mass-to-charge ratio of a cation is usually equal to the mass of the cation. -Turns are one of the most common structural motifs in proteins and change the direction of the peptide backbone by nearly 180, allowing the peptide chain to fold back onto itself. a Shanghai Institute of Organic Chemistry, Zhejiang Medicine Co., and Pharmaron postdoctoral fellowship (J.W. In other words, we assume the formal concentrations \(C_X\) of species in the buffer are equal to their actual concentrations \([X]\); we replace, \[pH=pK_a+\log_{10}\ \dfrac{[A^{-}]}{[HA]}\], \[pH=pK_a+ \log_{10}\ \dfrac{C_{A^-}}{C_{HA}}.\]. It is an indirect interaction between two nuclear spins that arises from hyperfine interactions between the nuclei and local electrons. Enantioselective total syntheses of ()-grayanotoxin III, (+)-principinol E, and ()-rhodomollein XX were accomplished based on a convergent strategy. Download Free PDF View PDF. & Weix, D. J. By submitting a comment you agree to abide by our Terms and Community Guidelines. [15][57] Notably, 1 possesses an uncommon tricyclo[6.2.0.02,6]decane motif and an unusual Bellemin-Laponnaz, S. Synthesis of N,O-heterocyclic carbene and coordination to rhodium(I) and copper(I). "[18] Structural relatives of adamantane are noradamantane and homoadamantane, which respectively contain one less and one more CH2 link than the adamantane. Get time limited or full article access on ReadCube. Reference; The following equation, which relates the pH of an aqueous solution of an acid to the acid dissociation constant of the acid, is known as the Henderson-Hasselbach equation. This technology represents a general strategy for the merger of in situ alcohol activation with transition metal catalysis. The unique 7-endo-trig cyclization based on a bridgehead Serving as a homoenolate precursor, 1,2-substituted cyclopropanols can now be converted to the corresponding cyclopropylamines via ring opening, intermolecular condensation with amines, and cyclization to reform the three-membered ring. [34], According to a statement from the family, the couple was driving to Rockford International Airport for a trip when their car became stuck in a ditch on a road near the landfill. Yang, C.-T. et al. It is also a noticeably poor approximation for weak acids/bases with relatively high ionization constants (say, \(K > 10^{-2}\)). Download Free PDF View PDF. Adamantane is the most stable isomer of C 10 H 16.The spatial arrangement of carbon atoms in the adamantane molecule is the same as in the 1 16, 15741585. Soc. 106, 26512710 (2006). This problem can be solved exactly (assuming all activity coefficients are equal to 1, which is generally a good approximation for solutions below about \(1\ mol\ L^{-1}\)). Synthesis and activity of ruthenium alkylidene complexes coordinated with phosphine and N-heterocyclic carbene ligands. [16], He discovered Negishi coupling, a process which condenses organic zinc compounds and organic halides under a palladium or nickel catalyst to obtain a C-C bonded product. In particular, the reaction with anisole proceeds under normal conditions and does not require a catalyst. Since the charge of cation formed in the mass spectrometer is almost always +1, the mass-to-charge ratio of a cation is usually equal to the mass of the cation. Metal-catalysed cross-couplings are a mainstay of organic synthesis and are widely used for the formation of CC bonds, particularly in the production of unsaturated scaffolds1. In mass spectroscopy, the mass-to-charge ratio (symbols: m/z, m/e) of a cation is equal to the mass of the cation divided by its charge. The Henderson-Hasselbach equation is derived from the definition of the acid dissociation constant as follows. The unique 7-endo-trig cyclization based on a bridgehead [2], Elastic constants of adamantane were measured using large (centimeter-sized) single crystals and the ultrasonic echo technique. Organic synthesis provides opportunities to transform drug discovery. The main absorption bands and their assignment are given in the table:[3]. 1: Butane and isobutane have the same molecular formula, C 4 H 10, but different structural formulas.. 55, 40404043 (2016). the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in In the first stage, the quantum system absorbs a photon of energy to assume a virtual state. Rev. The authors thank C. Liu and R. Lambert for assistance in preparing this manuscript. Reference; The following equation, which relates the pH of an aqueous solution of an acid to the acid dissociation constant of the acid, is known as the Henderson-Hasselbach equation. In the first stage, the quantum system absorbs a photon of energy to assume a virtual state. 125, 25462558 (2003). The initial stages of an enantioselective synthesis of (R)-1-hydroxy-7-methoxy-1,2,3,4-tetrahydronaphthalene-1-carboxylic acid required 26). The family said Suzuki was near the end of her battle with Parkinson's disease. However, consider the case when starting with a solution of \(\ce{HA}\) with initial concentration equal to \(9 \times 10^{-4}\ mol\ L^{-1}\). This is a weak monoprotic acid, so the initial solution must have \([H^+] < 9 \times 10^{-4}\ mol\ L^{-1}\) and thus \(pH\). Conjoining adamantane cages produces higher diamondoids, such as diamantane (C14H20 two fused adamantane cages), triamantane (C18H24), tetramantane (C22H28), pentamantane (C26H32), hexamantane (C26H30), etc. In mass spectroscopy, the mass-to-charge ratio (symbols: m/z, m/e) of a cation is equal to the mass of the cation divided by its charge. 130, 1258612587 (2008). Am. Suga, T. & Ukaji, Y. Nickel-catalyzed cross-electrophile coupling between benzyl alcohols and aryl halides assisted by titanium co-reductant. In particular, a robust and general method for the direct deoxygenative coupling of alcohols would have major implications for the field of organic synthesis. Influenza virus strains have developed drug resistance to amantadine and rimantadine, which are not effective against prevalent strains as of 2016. Photoredox catalysis has transformed the landscape of radical-based synthetic chemistry. prepared this manuscript. 2013, 70177027 (2013). A reducing sugar is a carbohydrate that is oxidized by a weak oxidizing agent (an oxidizing agent capable of oxidizing aldehydes but not alcohols, such as the Tollen’s reagent) in basic aqueous Its fragmentation results in weaker signals as m/z = 93, 80, 79, 67, 41 and 39. 116, 1256412649 (2016). The first adamantane derivative used as a drug was amantadine first (1967) as an antiviral drug against various strains of influenza[49] and then to treat Parkinson's disease. [12] In 1966 he resigned from Teijin, and became a postdoctoral associate at Purdue University, working under future Nobel laureate Herbert C. Brown. Organometallics 28, 64586461 (2009). *SeeSupplementary Information for experimental details. Therefore, butane and isobutane are constitutional isomers. For more than one century, photochemical [2+2]-cycloadditions have been used by synthetic chemists to make cyclobutanes, four-membered carbon-based rings. The molecule is both rigid and virtually stress-free. Prod. The silicon analogue of adamantane, sila-adamantane, was synthesized in 2005. Polyhedron 29, 3033 (2010). The resulting approximation breaks down in sufficiently dilute solution, and is already quite noticeable far before reaching water self-dissociation issues. Yurika Almanda. Everson, D. A., Jones, B. For a 0/90 geometry, quantum yield standards are typically fluorescent organic dyes of known quantum yield under specified experimental conditions (pH, solvent, and temperature) [66].As discussed in Section 7.7.4, to avoid quenching effects, all solutions should be degassed, and solvents and cuvettes should be of spectral grade and checked for spurious emission. This can be performed simply by diluting both the initial weak acid and strong base concentrations by 10 (i.e., \(100\ mL\) of \(0.09\ mol\ L^{-1}\) \(\ce{HA}\) plus \(50\ mL\) of \(0.09\ mol\ L^{-1}\) \(\ce{KOH}\) result in a buffer with acid/conjugate base concentrations of \(0.03\ mol\ L^{-1}\), and so on). Chem. Additions of radicals generated through photoredox catalysis to carboncarbon -bonds are well-established; however, this approach has yet to be applied to the functionalization of carboncarbon -bonds. A general method for the direct deoxygenative cross-coupling of free alcohols must overcome several challenges, most notably the in situ cleavage of strong CO bonds3, but would allow access to the vast collection of commercially available, structurally diverse alcohols as coupling partners4. Most reactions of adamantane occur via the 3-coordinated carbon sites. Before going into the calculations, it's quite simple to see an issue with the approximation in the second paragraph. A. The mass of the molecular ion is equal to the molecular weight of the compound. For a 0/90 geometry, quantum yield standards are typically fluorescent organic dyes of known quantum yield under specified experimental conditions (pH, solvent, and temperature) [66].As discussed in Section 7.7.4, to avoid quenching effects, all solutions should be degassed, and solvents and cuvettes should be of spectral grade and checked for spurious emission. Ei-ichi Negishi ( , Negishi Eiichi, July 14, 1935 June 6, 2021) was a Japanese chemist who was best known for his discovery of the Negishi coupling. Chem. Chiral Center, chiral atom, chirality center, or center of chirality is a tetrahedral atom in a molecule bearing four different ligands, with lone pairs, if any, treated as ligands. \(V_A\) is the volume of the weak acid solution being titrated and \(C^o_A\) is its formal initial concentration (before mixing and reacting with the base), while \(V_B\) is a variable volume of strong base solution added with formal initial concentration \(C^o_B\) (before mixing and reacting with the acid). With the proton concentration determined, the actual concentrations \([HA]\) and \([A^{-}]\) are compared with the formal concentrations \(C_{HA}\) and \(C_{A^{-}}\). [43] Aryl-substituted adamantane derivatives can be easily obtained starting from 1-hydroxyadamantane. Download Free PDF View PDF. The cover art illustrates the first intermolecular electrophilic trapping of metal ketone homoenolates. J. Let us consider the simple case of solutions of a weak monoprotic acid \(\ce{HA}\) with acid dissociation constant \(K_a\) where the concentration of acid and conjugate base are formally equal. Within the scope of analogous compounds created from the structure of In the second stage, it emits a photon of energy and either returns to the ground state or jumps into an excited state. However, IUPAC recommends using the name "adamantane".[1]. Within the scope of analogous compounds created from the structure of No funeral services took place in the United States, but his family planned to lay him to rest in Japan in 2022. Chem. We report herein a metallaphotoredox-based cross-coupling platform in which free alcohols are activated in situ by N-heterocyclic carbene salts for carboncarbon bond formation with aryl halide coupling partners. The left- and right-wing fragments were assembled via the diastereoselective Mukaiyama aldol reaction catalyzed by a chiral hydrogen bond donor. Chem. [23] The arrangement of carbon atoms is the same in adamantane and diamond. This indicates that the reaction occurs via an ionic mechanism. [48], All medical applications known so far involve not pure adamantane, but its derivatives. Two general types of monoalkenes are distinguished: terminal and internal. Soc. Eur. ADS eg. In organic chemistry, an alkene is a hydrocarbon containing a carboncarbon double bond.. Alkene is often used as synonym of olefin, that is, any hydrocarbon containing one or more double bonds. The principal value of the elasticity tensor, C11, was deduced as 7.52, 8.20, and 6.17 GPa for the <110>, <111>, and <100> crystalline directions. N-Bromosuccinimide As A Reagent In Organic ChemistryIn a blatant plug for the Reagent Guide, each Friday I profile a different reagent that is commonly encountered in Org 1/ Org 2.. N-Bromosuccinimide Is A More Convenient Alternative To Bromine (Br 2). J. Med. These encompass acyclic, cyclic, caged, bridgehead, fluoroalkyl, and benzylic acids, which were transformed to the corresponding Bpin esters smoothly. No headers. Enantioselective total syntheses of ()-grayanotoxin III, (+)-principinol E, and ()-rhodomollein XX were accomplished based on a convergent strategy. Article The right and left hands, wearing jeweled rings indicating individual reaction steps, lead to opposite enantioselection, Dinnocenzo, J. P. & Banach, T. E. Deprotonation of tertiary amine cation radicals. 126, 27632767 (2004). 57, No. Ye, Y., Chen, H., Sessler, J. L. & Gong, H. Zn-mediated fragmentation of tertiary alkyl oxalates enabling formation of alkylated and arylated quaternary carbon centers. Therefore, butane and isobutane are constitutional isomers. Inorganic Chemistry By GARY L. MIESSLER. ); a Crohns and Colitis Foundation of America fellowship (S.Y. CAS Choi, J. Therefore, butane and isobutane are constitutional isomers. 1-Hydroxyadamantane is readily formed by hydrolysis of 1-bromadamantane in aqueous solution of acetone. Lett. He spent most of his career at Purdue University in the United States, where he was the Herbert C. Brown Distinguished Professor and the director of the Negishi-Brown Institute. Peer review information Nature thanks the anonymous reviewer(s) for their contribution to the peer review of this work. The skeleton of 2 bore an unneeded carbon atom. Its structure was assigned on the basis of spectroscopic data and quantum chemical computational methods. [16] For comparison, the corresponding values for crystalline diamond are 1161, 1174, and 1123 GPa. He was awarded the 2010 Nobel 10, 383394 (2018). Chem. Thus, the mass-to-charge ratio of the molecular ion is equal to the molecular weight of the compound. It is used in some dry etching masks[46] and polymer formulations. This was removed by singlet oxygenation, to give the ,-unsaturated aldehyde, that was decarbonylated with an Ir catalyst to 16. Sakai, H. A., Liu, W., Le, C. & MacMillan, D. W. C. Cross-electrophile coupling of unactivated alkyl chlorides. The presence of substituents in a bicyclic compound doesnt affect the main rule for numbering which is to start it from one of the bridgehead carbon atoms and move in the direction of the larger ring towards Copper-catalyzed cross-coupling of nonactivated secondary alkyl halides and tosylates with secondary alkyl grignard reagents. Bridgehead nitrogen heterocycles which contain the quinazoline moiety synthesis and cycloaddition of 1,2-dihydroquinazoline 3-oxides. \[ HA + H_2O \rightleftharpoons A^- + H_3O^+\]. This page titled Mass-to-Charge Ratio is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Gamini Gunawardena via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. The skeleton of 2 bore an unneeded carbon atom. No headers. Santiago Pincay. Chemistry informer libraries: a chemoinformatics enabled approach to evaluate and advance synthetic methods. J. eg. 1988 - Organic Chemistry Laboratory Survival Manual. Zhao, L., Zhang, C., Zhuo, L., Zhang, Y. Yurika Almanda. Google Scholar. This page titled Reducing Sugar is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Gamini Gunawardena via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. We can reach the target concentrations of acid and conjugate base by adding \(50\ mL\) of strong base at the same concentration \(0.9\ mol\ L^{-1}\) (neutralizing half the original acid). If youve ever had the pleasure of working with bromine (Br 2), youll know that this dense orange liquid is a The molecule is both rigid and virtually stress-free. Alejandra Salazar. Legal. Slinker, J. D. et al. Vara, B. The following equation, which relates the pH of an aqueous solution of an acid to the acid dissociation constant of the acid, is known as the Henderson-Hasselbach equation. Notably, 1 possesses an uncommon tricyclo[6.2.0.02,6]decane motif and an unusual Therefore, its 16 hydrogen and 10 carbon atoms can be described by only two sites, which are labeled in the figure as 1 (4 equivalent sites) and 2 (6 equivalent sites). In November 1945, three months after World War II ended, they moved to Japan. [19], Boiling of adamantane with bromine results in a monosubstituted adamantane, 1-bromadamantane. Am. [5], Negishi was born in Hsinking (today known as Changchun), the capital of Manchukuo, in July 1935. Efficient yellow electroluminescence from a single layer of a cyclometalated iridium complex. After graduation from the University of Tokyo in 1958, Negishi did his internship at Teijin, where he conducted research on polymer chemistry. Am. Am. Reaction of either compound with acetonitrile affords the acetamide, which is hydrolyzed to give 1-adamantylamine:[45]. [13], In 1972, he became an assistant professor at Syracuse University, where began his lifelong study of transition metalcatalyzed reactions,[14] and was promoted to associate professor in 1979. a Shanghai Institute of Organic Chemistry, Zhejiang Medicine Co., and Pharmaron postdoctoral fellowship (J.W. & Fu, G. C. Transition metalcatalyzed alkyl-alkyl bond formation: another dimension in cross-coupling chemistry. These encompass acyclic, cyclic, caged, bridgehead, fluoroalkyl, and benzylic acids, which were transformed to the corresponding Bpin esters smoothly. Publishers note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. The following synthesis illustrates the enantioselective transacylation of a prochiral diol in organic solvent catalysed by a lipase. The presence of the self-dissociation constant of water \(k_w\) shows that it is being taken into consideration. (Wiley & Sons, 2016).pdf. Later, fluorination was achieved starting from adamantane itself. The 1H and 13C NMR chemical shifts are respectively 1.873 and 1.756 ppm and are 28.46 and 37.85 ppm. The left- and right-wing fragments were assembled via the diastereoselective Mukaiyama aldol reaction catalyzed by a chiral hydrogen bond donor. Soc. [3] He was 85 years old. Legal. 26", "Japanese Nobel Prize Chemists Honored By Royal Society Of Chemistry", "Police: No foul play in death of wife of Purdue Nobel Prize winner found in Illinois", "Autopsy: Hypothermia, complicated by Parkinson's and hypertension killed professor's wife", "Ei-ichi Negishi, Nobel Prize Winner in Chemistry, Dies at 85", "Japanese Nobel laureate chemist Negishi dies at 85", https://en.wikipedia.org/w/index.php?title=Ei-ichi_Negishi&oldid=1119679746, Foreign associates of the National Academy of Sciences, Pages containing links to subscription-only content, Short description is different from Wikidata, Articles containing Japanese-language text, Nobelprize template using Wikidata property P8024, Creative Commons Attribution-ShareAlike License 3.0, Sir Edward Frankland Prize Lectureship (2000), 1996 A. R. Day Award (ACS Philadelphia Section award), 1998 American Chemical Society Award for Organometallic Chemistry, 19982000 Alexander von Humboldt Senior Researcher Award, 2007 Gold Medal of Charles University, Prague, Czech Republic, 2010 ACS Award for Creative Work in Synthetic Organic Chemistry, 2015 Fray International Sustainability Award, SIPS 2015, 196061 FulbrightSmithMundt Fellowship, 196263 Harrison Fellowship at University of Pennsylvania, 2000 Sir Edward Frankland Prize Lectureship, 2009 Invited Lectureship, 4th Mitsui International Catalysis Symposium (MICS-4), Kisarazu, Japan, 2011 Order of the Griffin, Purdue University, This page was last edited on 2 November 2022, at 21:13. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Soc. Chem. Multiple substitution with bromine is achieved by adding a Lewis acid catalyst. A method for enantiodivergent production of S and R propargylic alcohols from their racemates by using commercial lipase-based dynamic kinetic resolution achieves quantitative conversion of the racemates into optically pure substances. In the second stage, it emits a photon of energy and either returns to the ground state or jumps into an excited state. 7, 39553959 (2017). 2: Ethyl alcohol and dimethyl ether have the same molecular Fanny Ainunnisa. Supplementary Figs. Bridgehead nitrogen heterocycles which contain the quinazoline moiety synthesis and cycloaddition of 1,2-dihydroquinazoline 3-oxides. 142, 72257234 (2020). It's an irony of modern organic chemistry that the simplest-looking carbon-carbon bonds are often the hardest to make. Article J. Chem. Int. [3] They married the next year and together they had two daughters. A direct experimental approach. [26] The simplicity of these spectra is consistent with high molecular symmetry. [17] Negishi also reported that organoaluminum compounds and organic zirconium compounds can be used for cross-coupling. \[-\log_{10}[H_3O^+] = -\log_{10} K_a - \log_{10} \dfrac{[HA]}{[A^-]}\], \[ pH = pK_a - \log_{10} \dfrac{[HA]}{[A^-]}\], \[ pH = pK_a + \log_{10} \dfrac{[A^-]}{[HA]} \label{HH}\]. Am. This was removed by singlet oxygenation, to give the ,-unsaturated aldehyde, that was decarbonylated with an Ir catalyst to 16. Password requirements: 6 to 30 characters long; ASCII characters only (characters found on a standard US keyboard); must contain at least 4 different symbols; Zhang, X. -Turns are one of the most common structural motifs in proteins and change the direction of the peptide backbone by nearly 180, allowing the peptide chain to fold back onto itself. Most reactions owe their efficiency to neighboring double bonds or oxygen and nitrogen atoms that linger in the products. [8], The first fluorinations of adamantane were conducted using 1-hydroxyadamantane[38] and 1-aminoadamantane as initial compounds. Dihydroquinazolinones as adaptative C(sp3) handles in arylations and alkylations via dual catalytic CC bond-functionalization. 26). The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. Barton, D. H. R. & McCombie, S. W. A new method for the deoxygenationof secondary alcohols. I'll set up the volumes and concentrations arbitrarily so we can reach the acid and conjugate base formal concentrations of \(0.3\ mol\ L^{-1}\) as mentioned in the question. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Trnka, T. M. et al. After looking at this first case, we shall investigate the effects of dilution by factors of 10. Download Free PDF View PDF. and D.W.C.M. No headers. [3][26], The infrared absorption spectrum of adamantane is relatively simple because of the high symmetry of the molecule. Soc. Chem. It can also be produced by ozonation of the adamantane:[42] Oxidation of the alcohol gives adamantanone. [14], Negishi began dating Sumire Suzuki in his freshman year and they announced their engagement to their parents in March 1958. After quenching of the excess triflic anhydride with 2-propanol, heating with base led to 2, presumably by way of the bridgehead carbocation 15. The saponification of -hydroxy esters can be readily undertaken using well-tested procedures that are very similar to those employed for the hydrolysis of conventional ester groups (see Section 5.02.2.1.1 and references therein). 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MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aglycone : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alcohol : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldaric_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldehyde : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alditol : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldol : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldol_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldol_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldonic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aldose : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alicyclic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aliphatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aliphatic_Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aliphatic_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkenyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkenyl_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkenyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkenyl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkenyl_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkoxide_ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkoxy_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkylborane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_sulfonate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Substitution : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ambident_Nucleophile : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine_Oxide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Residue : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Unit : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ammonium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amphoteric : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anchimeric_Assistance : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Angle_Strain : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Anti-Markovnikov_Addition" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anticoplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiparallel : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiperiplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aprotic_Solvent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenesulfonic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Assisted_Homolysis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Asymmetric_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Autoxidation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Axial_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", A_Value : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Baeyer-Villiger_Oxidation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Peak : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Strength : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beckmann_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Beer-Lambert_Law" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzene_Ring : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzilic_Acid_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne_Mechanism : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Betaine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Birch_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Boat_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Angle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Axis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Dissociation_Energy : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Branched_Alkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridge : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridged_Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridgehead_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Brnsted-Lowry_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bromohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "C-Terminal" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cahn-Ingold-Prelog_Convention" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbenoid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocycle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbohydrate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Oxygen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylate_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Derivative : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Salt : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Hydrogenation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Center_of_Chirality : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CFB : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chair_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemically_Equivalent_Ligands : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Ionization : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Shift : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemoselective : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chirality_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Molecule : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorofluorocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromate_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CIP_Convention : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cis-Trans_Isomers" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Clemmensen_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Combustion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Concerted_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Condensation_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Configuration : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Diene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Double_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutionally_Heterotopic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutional_Isomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coordination_Number : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Elimination : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Constant : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.